Swirls in the solar corona

This project has received funding from the European Research Council (ERC) under the European Union’s Horizon 2020 research and innovation program (grant agreement No. 695075).Context. Vortex flows have been found in the photosphere, chromosphere, and low corona in observations and simulations. It has been suggested that vortices play an important role in channeling energy and plasma into the corona. However, the impact of vortex flows on the corona has not been studied directly in a realistic setup. Aims. We investigate the role vortices play for coronal heating using high-resolution simulations of coronal loops. The vortices are not artificially driven and they arise, instead, self-consistently from magnetoconvection. Methods. We performed 3D resistive (magnetohydrodynamic) MHD simulations with the MURaM code. Studying an isolated coronal loop in a Cartesian geometry allows us to resolve the structure of the loop interior. We conducted a statistical analysis to determine vortex properties as a function of height from the chromosphere into the corona. Results. We find that the energy injected into the loop is generated by internal coherent motions within strong magnetic elements. A significant part of the resulting Poynting flux is channeled through the chromosphere in vortex tubes forming a magnetic connection between the photosphere and corona. Vortices can form contiguous structures that reach up to coronal heights, but in the corona itself, the vortex tubes get deformed and eventually lose their identity with increasing height. Vortices show increased upward directed Poynting flux and heating rate in both the chromosphere and corona, but their effect becomes less pronounced with increasing height. Conclusions. While vortices play an important role for the energy transport and structuring in the chromosphere and low corona, their importance higher up in the atmosphere is less clear since the swirls are less distinguishable from their environment. Vortex tubes reaching the corona reveal a complex relationship with the coronal emission.Publisher PDFPeer reviewe

Low Ply Drawings of Trees

We consider the recently introduced model of \emph{low ply graph drawing}, in which the ply-disks of the vertices do not have many common overlaps, which results in a good distribution of the vertices in the plane. The \emph{ply-disk} of a vertex in a straight-line drawing is the disk centered at it whose radius is half the length of its longest incident edge. The largest number of ply-disks having a common overlap is called the \emph{ply-number} of the drawing. We focus on trees. We first consider drawings of trees with constant ply-number, proving that they may require exponential area, even for stars, and that they may not even exist for bounded-degree trees. Then, we turn our attention to drawings with logarithmic ply-number and show that trees with maximum degree $6$ always admit such drawings in polynomial area.Comment: This is a complete access version of a paper that will appear in the proceedings of GD201

Electrostatic attraction of nanoobjects - a versatile strategy towards mesostructured transition metal compounds

This highlight summarizes current challenges of mesostructuring and focuses on the scope and the potential of the ELAN – (electrostatic attraction of nanoobjects) strategy in mesostructuring of transition metal compounds. It discusses the limitations of this concept and highlights prominent examples. ELAN exploits the Coulomb attraction between inorganic precursors and polymeric templates in order to prevent macrophase separation. Essential requirements for ELAN are tailor-made, mesoscopic polyelectrolytic templates and charged molecular oligo-ions or stable colloids carrying a surface charge. The ELAN-strategy is highly reliable and opens the way to crystalline, mesoporous transition metal compounds with predefined polymorphism. It also provides the possibility to adjust wall chemistry and reactivity as well as the flexibility to synthesise different mesostructures (spheres, non-woven arrays or hexagonally ordered phases)

Mesostructured ZnO/Au nanoparticle composites with enhanced photocatalytic activity

Ease of catalyst separation from reaction mixtures represents a significant advantage in heterogeneous photocatalytic wastewater treatment. However, the activity of the catalyst strongly depends on its surface-to-volume ratio. Here, we present an approach based on cylindrical polybutadiene-block-poly(2-vinylpyridine) polymer brushes as template, which can be simultaneously loaded with zinc oxide (ZnO) and gold (Au) nanoparticles. Pyrolytic template removal of the polymer yields in mesostructured ZnO/Au composites, showing higher efficiencies in the photocatalytic degradation of ciprofloxacin and levofloxacin (generic antibiotics present in clinical wastewater) as compared to neat mesostructured ZnO. Upscaling of the presented catalyst is straightforward promising high technical relevance

Rapid Low-Dimensional Li+Ion Hopping Processes in Synthetic Hectorite-Type Li0.5[Mg2.5Li0.5]Si4O10F2

Understanding the origins of fast ion transport in solids is important to develop new ionic conductors for batteries and sensors. Nature offers a rich assortment of rather inspiring structures to elucidate these origins. In particular, layer-structured materials are prone to show facile Li+ transport along their inner surfaces. Here, synthetic hectorite-type Li0.5[Mg2.5Li0.5]Si4O10F2, being a phyllosilicate, served as a model substance to investigate Li+ translational ion dynamics by both broadband conductivity spectroscopy and diffusion-induced 7Li nuclear magnetic resonance (NMR) spin-lattice relaxation experiments. It turned out that conductivity spectroscopy, electric modulus data, and NMR are indeed able to detect a rapid 2D Li+ exchange process governed by an activation energy as low as 0.35 eV. At room temperature, the bulk conductivity turned out to be in the order of 0.1 mS cm-1. Thus, the silicate represents a promising starting point for further improvements by crystal chemical engineering. To the best of our knowledge, such a high Li+ ionic conductivity has not been observed for any silicate yet